Hierarchical Structure‐Within‐Structure Morphologies in A2‐star‐(B‐alt‐C) Molecules

We employ dissipative particle dynamics (DPD) to examine the self‐assembly behavior of A₂‐star‐(B‐alt‐C) molecules. We successfully observe various types of hierarchical structure‐within‐structures, such as A‐formed spheres in the matrix formed by B and C alternating layers, hexagonally packed A‐formed cylinders in the matrix with B and C segregated layers, B and C alternating layers‐within‐lamellae, coaxial B and C alternating domains within hexagonally packed BC‐formed cylinders in the A‐matrix, and co‐centric BC‐alternating domains within BC‐formed spheres in the A‐matrix, by increasing the A composition. Generally speaking, the small length‐scale B and C segregated domains are in parallel to the large length‐scale structures. This hierarchical periodicity along the same axis as well as the various characteristic structures, that the A₂‐star‐(B‐alt‐C) copolymers display, are quite different from those in A‐block‐(B‐graft‐C) coil‐comb copolymers. Moreover, it is interesting to find that when the copolymer chain length increases, though the hierarchical structure type is maintained, the number of small length‐scale lamellae that can form within the large length‐scale structure increases. These hierarchical structures under various compositions are reported theoretically for the first time in the copolymer systems consisting of the alternating blocks, and are in good agreement with the most recent experimental work by Matsushita and co‐workers (Macromolecules 2007 , 40, 4023).     

N,N-二(2-苯并咪唑亚甲基)甲胺高氯酸盐的晶体和电子结构

合成了三齿配体N,N-二(2-苯并咪唑亚甲基)甲胺(MN3)的高氯酸盐.对该化合物进行了元素分析、紫外和红外表征;采用X射线衍射方法测定了该化合物的晶体结构,依据晶体结构数据使用G98程序对配体(MN3)进行了量子化学计算.     

Untersuchungen des Hydroxylammonium-Fluorogallats

Summary Crystals of (NH₃OH)₃GaF₆ have been isolated from aqueous solution. The compound crystallizes triclinic, with cell parametersa=6.539(5) Å,b=6.924(5) Å,c=9.403(1) Å, =87.01(9)°, =83.98(8)°, =70.28(8)°. The thermal decomposition was studied by TG and DSC analysis.

     

Synthesis and Crystal Structure of 4,5-Diazafluorene-9-one Azine Hydrochloride Hydrate

1 INTRODUCTION During the study of polynuclear complexes with the aim to investigate the magnetic super-exchange interaction between the adjacent metal ions bridged by a conjugation molecule[1], we have made efforts to prepare complexes bridged by 4, 5-diazafluorene-9-one azine (DAA) and found that the coordination ability of DAA is poor in the acidic solution. In order to probe the reason, DAA has been crystallized from the hydrochloric acid solution and its crystal structure has b…     

活性酚醛树脂中羟甲基含量的测定

本文提出一种酚醛树脂中羟甲基含量的化学分析法，分别以＾１３ＣＮＭＲ和化学分析法测定酚醛树脂的羟甲基含量。将两种测试结果与已知的投料量进行比较，证明所建立的化学分析法可行。     

Synthesis and Structure of(NH4)_2 [V2O_4(OCH_2COO)_2]

ＳｙｎｔｈｅｓｉｓａｎｄＳｔｒｕｃｔｕｒｅｏｆ（ＮＨ４）２［Ｖ２Ｏ４（ＯＣＨ２ＣＯＯ）２］ＺＨＯＵＺｈａｏ－ｈｕｉ，ＷＡＮＧＪｉｎｚｈｉ，ＷＡＮＨｕｉ－ｌｉｎａｎｄＴＳＡｌＫｈｉ－ｒｕｉ（ＤｅｐａｒｔｍｅｎｔｏｆＣｈｅｍｉｓｔｒｙ，ＸｉａｍｅｎＵｎｉ...     

Crystal structure of the 2:1 acetonitrile complex of 18-crown-6

Single crystal X-ray analysis of the 2:1 acetonitrile complex of 18-crown-6 is reported. Crystals of the complex are monoclinic,P2₁/n, witha=9.123(3),b=8.524(3),c=13.676(4) Å, =104.68(3)°, andD _c =1.118 g cm^–3 forZ=2. The complex lies on a center of symmetry, with the crown in theD _3d conformation. Methyl groups of the acetonitrile molecules have weak interactions with the crown oxygen atoms, and are tilted 31.7° from the host's threefold axis. Methyl hydrogen atoms are rotationally disordered about the acetonitrile axis. Supplementary Data relating to this article are deposited with the British Library as Supplementary Publication No. SUP 82057 (12 pages).     

α-异丙基、β-异丁基丙烯酸希土配合物的合成和配位性质研究

本文制备了α-异丙基、β-异丁基丙烯酸的15种希土配合物RE(C₉H₁₇COO)₃,用X射线多晶粉末衍射、电子光谱、红外光谱和热重差热分析方法研究了配合物中RE-O键的成键性能以及羧基的配位性质.配合物中存在两种不同的羧基配位形式,轻中希土配合物(La,Ce,Pr,Nd,Sm,Eu)中羧基具有不对称桥式双齿配位形式,而重希土配合物(Gd,Tb,Dy,Ho,Er,Tm,Yb,Lu,Y)中羧基具有对称螯合双齿配位形式,配位形式的不同使得希土配合物呈现两种不同的多晶衍射图和热分解过程.     

Morphological and Structural Studies of sPS/aPS Blends

Inrecentyears,thenewsedricrystallinepolymersyndiotacticp0lystyrene(sPS)hasat-ITactedmuchattentionduetoitsg0odchendcalresistanceandenhancedmechanicalperformanceatelevatedtemPeratUre.'H0wever,itexhibitshighbrittlenessandpoorimPact-resistanceandtCar-resistance.2Therefore,itisnecessarytomodifyitwithtougheningpolyIners.AsimPlemeth0dto0verc0methedriscibilityofatwo-phaseblendofsPSandatougheningpolymristotwrovetheinterfacialaffmity,wheretheadditionofablockcoP0lymerisconsideredtobemosteffective.3…